How to determine the hardness of water
By edta method / complexometric method :-
EDTA stands for ethylenediaminetetra acetic acid This method is widely used for the determination of hardness of water because it is more accurate than the soap titration method.
edta is a strong complexing agent.
as edta is not soluble in water but it is soluble in disodium salt so it is generally used in complexometric titration.
the complexing property of edta is used to estimate the amount of hardness causing ions in the water sample.
so that the water sample buffered at PH=9 to 10 is titrated against EDTA using eriochrome black-T which is also known as EBT indicator
EBT (eriochrome black-t) indicator is a blue coloured azo dye which is capable of forming soluble wine-red coloured complexes with calcium and magnesium
principle :-
This method is based on the fact that bivalent hardness causing metal ions (calcium and magnesium ion) which is present in the hard water is able to form complexes with both eriochrome black-t (ebt) as well as ethylenediaminetetraacetic acid (edta).
but the edta complexes are more stable as compared to ebt indicator
1 When ebt indicator is added to the sample of hard water then it forms a wine red colour compound which is a unstable compound
2 On addition of edta it first combines with free metal ions to give very stable and colourless metal ion-edta complex then the metal ion indicator comlex
3 When all the free metal ion gets complexed with edta further addition of edta solution displace the ebt indicator from metal-ebt complex since the stability of complexes (metal-edta) is very high than metal-ebt complex
now the free indicator shows blue colour in solution at ph=9 to 10 so that at the end point of the titration the colour of the titration turns wine red colour to blue colour
calamite is also use as indicator because of behaviour is identical to eriochrome black-t
thus the amount of edta used corresponds to the total hardness of water.
but the temporary hardness of the water can be easily removed by simply boiling of water and after the removal of precipitate by filtration the permanent hardness of the water can be determined by the titration and temporary hardness will be given by the difference of total hardness and permanent hardness.
Procedure :-
Preparation of solution :-
1. preparation of standard hard water :-
For the preparation of shw (standard hard water) dissolve one gram of pure and dry calcium carbonate in minimum quantity of of dilute hcl and boil it
this solution is evaporated to dryness to remove excess of hcl and co2
the residue is dissolve in distilled water and make up the solution upto one litre
2. preparation of edta solution :-
For the preparation of edta solution dissolve 3.72g of disodium salt of edta in distilled water and make up to 1000ml, 0.01m edta is prepared.
3. preparation of buffer solution :-
For the preparation of buffer solution for the process weight out of 67.5 g of NH4CL and dissolve this in 570 mL of concentration ammonia solution and make upto 1 litre with distilled water.
4. preparation of eriochrome black-t solution :-
For the preparation of eriochrome black-t solution you need to dissolve 0.5 g of eriochrome black-t on 100mL of alcohol
Determinations of hardness :-
standardization of EDTA method :-
for this you need to fill up the burate with the edta solution. pipette out 50 mL of standard hard water into the conical flask. then after you need to add 10 mL of buffer solution of pH value across 9-10 and add 2-3 drops of eriochrome black-t. titrate this solution against EDTA until the wine-red colour, changes to blue (due to EBT)
for the calculation purpose let the value of EDTA used in the process be V1 mL.
determination of total hardness :-
It also follows the same procedure which is mentioned above, then after titrating 50 ml of unknown water sample against EDTA. let the volume of EDTA used this time will be as V2 ml.
determination of permanent hardness :-
For the determination of permanent hardness you need to take 250 ml of the water sample in a 500 ml and you have to boil it till the volume reduce to about 50 ml and also this step causes all the bicarbonates decomposes into insoluble calcium carbonate and magnesium hydroxide. filter and wash the precipitate with distilled water and quantitatively collect the filtrate and washing in 250 ml conical flask and make up the volume to 250 ml with distilled water. titrate 50 ml of this water sample against EDTA and also let the volume used here be V3 ml.
While performing this process in a chemistry laboratory you need to take care of certain precautions for the successful completion of the reaction.
and also it is required to perform actions in the guidance of a lab assistant or some faculty member.
I hope the mentioned above information helps to getting much knowledge about the hardness of water
Thankyou and have an amazing day.
BY :- ADARSH GUPTA